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- W2029017030 abstract "Abstract Hydrolysis of bis (hydroxyaryl) tellurium (IV) dihalide appears to proceed in a stepwise manner. In neutral medium products of the type R2Te (OH)X (X = halide ion, R = 4-hydroxyphenyl and 3-methyl-4-hydroxy-phenyl) have been isolated. Further hydrolysis does not occur appreciably. Alkali hydrolysis (with NaCH) yields R2Te (OH)2 which on heating at 100°C or aging changes to R2TeO type species. Isolation of the intermediates in this case is not possible but they are indicated by pH-metric and conductometric titrations. Hydrolysis of these compounds follows the order Cl> Br> I and, o-cresol > phenol. R2Te (OH)X, R2Te (OH) 2 and R2TeO type species thus isolated have been charac-terized by elemental analyses, IR, 1H and mass spectral studies. Mechanisms for the hydrolysis is proposed." @default.
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- W2029017030 date "1984-01-01" @default.
- W2029017030 modified "2023-10-14" @default.
- W2029017030 title "Preparative and Spectral Studies on the Products of Diaryltellurium (IV) Dihalide Hydrolysis" @default.
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- W2029017030 doi "https://doi.org/10.1080/00945718408058273" @default.
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