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• W2029017380 startingPage "5032" @default.
• W2029017380 abstract "Threshold photoelectron−photoion coincidence spectroscopy (TPEPICO) has been used to investigate the gas-phase ionic dissociation energies and thermochemistry of Me4Ge and Me3GeX, (Me = methyl; X = Cl, Br) molecules. The 0 K dissociation onsets for these species have been measured from the breakdown diagram and the ion time-of-flight distributions, which were modeled with the statistical RRKM theory and DFT calculations. The measured 0 K dissociative photoionization onsets were as follows: Me3Ge+ + Me (9.826 ± 0.010 eV); Me3Ge+ + Cl (10.796 ± 0.040 eV); Me3Ge+ + Br (10.250 ± 0.011 eV); Me2GeCl+ + Me (10.402 ± 0.010 eV); and Me2GeBr+ + Me (10.333 ± 0.020 eV). These onsets were used to obtain new values for (in kJ/mol) of the neutral molecules Me3GeCl (−239.8 ± 5.7) and Me3GeBr (−196.5 ± 4.3), and also for the following ionic species: Me3Ge+ (682.3 ± 4.1), Me2GeCl+ (621.1 ± 5.8), and Me2GeBr+ (657.8 ± 4.7)." @default.
• W2029017380 created "2016-06-24" @default.
• W2029017380 creator A5005819552 @default.
• W2029017380 creator A5009954577 @default.
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• W2029017380 date "2006-03-30" @default.
• W2029017380 modified "2023-10-03" @default.
• W2029017380 title "Threshold Photoelectron−Photoion Coincidence Spectroscopy: Dissociation Dynamics and Thermochemistry of Ge(CH₃)₄, Ge(CH₃)₃Cl, and Ge(CH₃)₃Br" @default.
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• W2029017380 doi "https://doi.org/10.1021/jp060264t" @default.
• W2029017380 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16610821" @default.
• W2029017380 hasPublicationYear "2006" @default.
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