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- W2029017679 abstract "Reaction of HCHO with B 10 H 14 under aqueous alkaline conditions yields the arachno 10-vertex [6-CB 9 H 14 ] - anion 2 (60%) which upon solid-state thermolysis as its Cs + salt yields the closo 9-vertex [4-CB 8 H 9 ] - anion 1 (45%). MeCHO reacts similarly to give the C -methylated arachno [6-Me-6-CB 9 H 13 ] - anion 4 (37%) which upon thermolysis gives the closo [4-Me-4-CB 8 H 8 ] - anion 3 (72%). PhCHO with B 10 H 14 under alkaline conditions gives the nido 10-vertex [6-Ph-6-CB 9 H 11 ] - anion 6 (85%) which upon thermolysis of its [NEt 4 ] + salt gives the closo [4-Ph-4-CB 8 H 8 ] - anion 5 (73%). In a preliminary iodination investigation, unsubstituted closo anion 1 with elemental I 2 in CH 2 Cl 2 gives approximately equimolar closo [4-CB 8 H 8 -3-I] - 12 and closo [4-CB 8 H 8 -5-I] - 13 ( ca 60%) and smaller amounts of closo [4-CB 8 H 7 -5,6-I 2 ] - 14 (12%). The [NEt 4 ] + salts of 1 , 3 and 5 are characterised crystallographically, as is the [PMePh 3 ] + salt of 12 ." @default.
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- W2029017679 date "2002-01-01" @default.
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- W2029017679 title "Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System" @default.
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