Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029039650> ?p ?o ?g. }
- W2029039650 endingPage "50" @default.
- W2029039650 startingPage "36" @default.
- W2029039650 abstract "The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CHCHR′)(CO)(PR3)2L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR3)2L}2(μ-CHCH-bridge-CHCH) and on heterobinuclear systems where only one of the two redox-active metal–organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl(CO)(PR3)2L(CHCH–) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR3)2L} and CHCHR′ constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo- and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites. Aspects of this work include examples of complexes showing time-dependent valence trapping, complexes aimed at delineating the efficiencies of through-space versus through-bond pathways for electron delocalization, complexes where electrostatic effects on the redox splitting ΔE1/2 dominate over those from the resonance contribution and systems that exhibit extensive charge and spin delocalization between two dislike endgroups despite their intrinsically different redox potentials." @default.
- W2029039650 created "2016-06-24" @default.
- W2029039650 creator A5044618446 @default.
- W2029039650 creator A5059647078 @default.
- W2029039650 creator A5065632744 @default.
- W2029039650 creator A5067859993 @default.
- W2029039650 date "2011-08-01" @default.
- W2029039650 modified "2023-10-17" @default.
- W2029039650 title "Vinyl-ruthenium entities as markers for intramolecular electron transfer processes" @default.
- W2029039650 cites W1479839242 @default.
- W2029039650 cites W1491133765 @default.
- W2029039650 cites W1835764176 @default.
- W2029039650 cites W1964671262 @default.
- W2029039650 cites W1968355139 @default.
- W2029039650 cites W1969849325 @default.
- W2029039650 cites W1971016000 @default.
- W2029039650 cites W1972361342 @default.
- W2029039650 cites W1974127696 @default.
- W2029039650 cites W1976616002 @default.
- W2029039650 cites W1978152525 @default.
- W2029039650 cites W1979568951 @default.
- W2029039650 cites W1983009723 @default.
- W2029039650 cites W1987436930 @default.
- W2029039650 cites W1987935734 @default.
- W2029039650 cites W1989191794 @default.
- W2029039650 cites W1991810916 @default.
- W2029039650 cites W1994074263 @default.
- W2029039650 cites W1996123153 @default.
- W2029039650 cites W1997204226 @default.
- W2029039650 cites W1997865923 @default.
- W2029039650 cites W2000857390 @default.
- W2029039650 cites W2001173915 @default.
- W2029039650 cites W2002266779 @default.
- W2029039650 cites W2002607452 @default.
- W2029039650 cites W2003869040 @default.
- W2029039650 cites W2005340565 @default.
- W2029039650 cites W2008221418 @default.
- W2029039650 cites W2008942182 @default.
- W2029039650 cites W2009367217 @default.
- W2029039650 cites W2011278098 @default.
- W2029039650 cites W2013232915 @default.
- W2029039650 cites W2016547684 @default.
- W2029039650 cites W2017798162 @default.
- W2029039650 cites W2017824551 @default.
- W2029039650 cites W2019330754 @default.
- W2029039650 cites W2019999126 @default.
- W2029039650 cites W2020695901 @default.
- W2029039650 cites W2021181893 @default.
- W2029039650 cites W2023177859 @default.
- W2029039650 cites W2023525861 @default.
- W2029039650 cites W2024188322 @default.
- W2029039650 cites W2025507031 @default.
- W2029039650 cites W2026850798 @default.
- W2029039650 cites W2027850176 @default.
- W2029039650 cites W2029078755 @default.
- W2029039650 cites W2031223934 @default.
- W2029039650 cites W2032117125 @default.
- W2029039650 cites W2032451767 @default.
- W2029039650 cites W2032587009 @default.
- W2029039650 cites W2032657118 @default.
- W2029039650 cites W2034073120 @default.
- W2029039650 cites W2035317789 @default.
- W2029039650 cites W2039234535 @default.
- W2029039650 cites W2039376130 @default.
- W2029039650 cites W2039459422 @default.
- W2029039650 cites W2040338073 @default.
- W2029039650 cites W2040865037 @default.
- W2029039650 cites W2041711882 @default.
- W2029039650 cites W2042037657 @default.
- W2029039650 cites W2044931258 @default.
- W2029039650 cites W2045295270 @default.
- W2029039650 cites W2045960816 @default.
- W2029039650 cites W2046881079 @default.
- W2029039650 cites W2052409934 @default.
- W2029039650 cites W2053504597 @default.
- W2029039650 cites W2053597722 @default.
- W2029039650 cites W2056381273 @default.
- W2029039650 cites W2058164610 @default.
- W2029039650 cites W2060539938 @default.
- W2029039650 cites W2060757838 @default.
- W2029039650 cites W2060946665 @default.
- W2029039650 cites W2061183479 @default.
- W2029039650 cites W2061772440 @default.
- W2029039650 cites W2065531464 @default.
- W2029039650 cites W2067334544 @default.
- W2029039650 cites W2068087228 @default.
- W2029039650 cites W2070263369 @default.
- W2029039650 cites W2071776811 @default.
- W2029039650 cites W2072148697 @default.
- W2029039650 cites W2078528732 @default.
- W2029039650 cites W2080902624 @default.
- W2029039650 cites W2081314287 @default.
- W2029039650 cites W2085293257 @default.
- W2029039650 cites W2089347010 @default.
- W2029039650 cites W2110714673 @default.
- W2029039650 cites W2137143835 @default.
- W2029039650 cites W2138289499 @default.
- W2029039650 cites W2158547866 @default.