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- W2029041857 abstract "Physicochemical parameters for adsorption of gases at the submonolayer regions of heterogeneous solid surfaces are measured experimentally as a function of time, and then interrelated as local isotherms θ against adsorption energy ε, fractional changes of adsorption sites f(ε)/c*max against ε, θ against f(ε)/c*max, and distribution functions θ f(ε)/c*max over adsorption energy values ε, without using at all the well-known integral equation Θ(p, T)=∫∞0θ(p, T, ε)f(ε)dε and assumptions concerning the pair f(ε) and θ(p, T, ε). The method uses only chromatographic experimental data obtained by the inverse gas chromatography technique known as reversed-flow gas chromatography. It has been applied to the adsorption of cis-2-butene and trans-2-butene onto particles of Penteli marble at temperatures of 302, 314, 323, and 333 K. The results obtained are comparable with those calculated on the basis of the well-known integral equation." @default.
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- W2029041857 date "2001-07-01" @default.
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- W2029041857 title "Interrelations between Adsorption Energies and Local Isotherms, Local Monolayer Capacities, and Energy Distribution Functions, as Determined for Heterogeneous Surfaces by Inverse Gas Chromatography" @default.
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- W2029041857 doi "https://doi.org/10.1006/jcis.2001.7478" @default.
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