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• W2029047031 startingPage "5496" @default.
• W2029047031 abstract "An EC/DEC [40:60% (v/v)] solvent mixture has been added in various amounts to the ionic liquid (IL) hexyltrimethylammonium bis(trifluoromethylsulfonyl)imide (N1116-NTf2) in the presence of LiNTf2 (lithium bis(trifluoromethylsulfonyl)imide) as lithium salt for possible use as electrolytes in lithium-ion batteries. These electrolytes exhibit a larger thermal stability than the reference electrolyte EC/DEC [40:60] + LiNTf2 1 M when the percentage of the IL exceeds 30% (v/v). All studied electrolytes are glass forming ones with an ideal glass transition temperature of ca. −85 °C(±5 °C), which has been determined by application of the VTF theory to conductivity and viscosity measurements and confirmed by DSC (Tg = −90 ± 5 °C). An electrochemical window of about 5 V versus Li/Li+ was measured at a glassy carbon electrode. The cycling ability of the optimized electrolyte N1116-NTf2/EC:DEC (40/60% (v/v)) + 1 M LiNTf2 has been investigated at a titanate oxide (Li4Ti5O12) and a cobalt oxide (LixCoO2) electrodes. Cycling the positive and the negative electrodes was conducted successfully with a high capacity and without any significant fading." @default.
• W2029047031 created "2016-06-24" @default.
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• W2029047031 date "2008-07-01" @default.
• W2029047031 modified "2023-10-14" @default.
• W2029047031 title "Solvents in salt electrolyte: Benefits and possible use as electrolyte for lithium-ion battery" @default.
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• W2029047031 doi "https://doi.org/10.1016/j.electacta.2008.03.012" @default.
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