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- W2029047051 abstract "Abstract Three novel Cu(II) compounds Cu(2 aepy )Pd(CN) 4 ( 1 ), Cu(3 aepy )Pd(CN) 4 H 2 O ( 2 ) and [Cu(4 aepy ) 2 (H 2 O) 2 ][Pd(CN) 4 ] ( 3 ) (X aepy = X(2-aminoethylpyridine), X = 2,3,4) were isolated in single crystal form from the aqueous systems Cu 2+ – X aepy – [Pd(CN) 4 ] 2– . The resulting crystal structures depend on the position of 2-aminoethyl arm on the pyridine ring: 1 exhibits a three-dimensional (3d) polymeric structure and only one chelating 2 aepy ligand is ligated to the pentacoordinated Cu(II) atom ( τ = 50%); the crystal structure of 2 features a puckered 2d polymer formed by hexacoordinated Cu(II) atoms (4 + 1 + 1 form) and [Pd(CN) 4 ] 2– anions linked by bridging cyanido ligands; and the Cu(II) atoms are additionally bridged by 3 aepy ligands. The crystal structure of 3 is built up of positively charged chains in which [Cu(H 2 O) 2 ] 2+ fragments are linked by a pair of 4 aepy ligands, giving hexacoordinated Cu(II) in the 4 + 2 form, with [Pd(CN) 4 ] 2– counter anions. Hydrogen bonds reinforce the crystal structures of 1 – 3 . Variable temperature magnetic studies based on susceptibility and magnetization measurements down to 2 K reveal that 1 deviates from Curie–Weiss behavior at low temperature, while 2 and 3 exhibit Curie–Weiss behavior with θ values of −0.85 K and −0.46 K for 2 and 3 , respectively." @default.
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- W2029047051 date "2014-08-01" @default.
- W2029047051 modified "2023-09-26" @default.
- W2029047051 title "Tetracyanidopalladates of Cu(II) with 2-aminoethylpyridines as blocking ligands: The role of the 2-aminoethyl arm position on the pyridine ring" @default.
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- W2029047051 doi "https://doi.org/10.1016/j.molstruc.2014.04.061" @default.
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