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- W2029055828 abstract "In connection with the possible use of hydrocarbons as fuels for hypersonic aircraft, investigations are being made on the thermal stability of prototype fuels at temperatures up to 1000°F. The presence of oxygen has a deleterious effect on the observed thermal stability, as measured by a high temperature coker, even at concentrations in the sub-ppm region. After developing a GLC method for determining oxygen in hydrocarbons down to 10 ppb, the effect of O2 was explored with decalin at concentrations down to the level of detection. No effect was noted at Oz concentrations up to ca 3 ppm but thereafter it was found that thermal stability decreased rapidly with increasing equilibrium oxygen concentration in the range up to about 10 ppm, more slowly up to about 15 ppm, and showed little subsequent response up to the saturation limit (ca 300 ppm). Methylcyclohexane and a naphthenic jet fuel were not investigated as completely but demonstrated somewhat similar but individual behaviors. It appears that the depositing tendency of the fuel is generally related to the basic kinetics of the oxidation of hydrocarbons but the reasons for the idiosyncracies of individual hydrocarbons are obscure." @default.
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- W2029055828 date "1971-10-01" @default.
- W2029055828 modified "2023-09-28" @default.
- W2029055828 title "Effect of oxygen concentration on the thermal stability of naphthenes" @default.
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- W2029055828 doi "https://doi.org/10.2514/3.44307" @default.
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