Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029063625> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2029063625 endingPage "50" @default.
- W2029063625 startingPage "45" @default.
- W2029063625 abstract "Abstract Carboxylic acids are valuable chemical products, which can be produced efficiently by catalytic oxidation of various organic compounds using vanadium-based catalysts. Degradation resistance of carboxylic acids under applied reaction conditions is an important factor influencing selectivity of such reactions. This paper addresses the oxidative and non-oxidative gas phase degradation of formic, acetic and propionic acids over V 2 O 5 /TiO 2 and MoVTeNb mixed oxides. Formic acid has been found to undergo mainly acid catalyzed decarbonylation, regardless the presence or absence of oxygen in the feed. Both acetic and propionic acids underwent oxidation (in aerobic conditions) through one-carbon degradation steps until CO and CO 2 were produced. The mechanistic aspects of these transformations are discussed. The key intermediacy of 2-(hydro)peroxy carboxylic acids is suggested, based on the nature of primary reaction products. The catalytic activity of MoVTeNb mixed oxides toward oxidative and non-oxidative degradation of acetic and propionic acids appeared notably lower compared to that of V 2 O 5 /TiO 2 . This may be linked to the enhanced efficiency of the former catalyst in selective oxidation of organic substrates to carboxylic acids." @default.
- W2029063625 created "2016-06-24" @default.
- W2029063625 creator A5031054717 @default.
- W2029063625 creator A5052246045 @default.
- W2029063625 date "2013-09-01" @default.
- W2029063625 modified "2023-09-26" @default.
- W2029063625 title "Oxidative and non-oxidative degradation of C1–C3 carboxylic acids over V2O5/TiO2 and MoVTeNb oxides: A comparative study" @default.
- W2029063625 cites W1409897175 @default.
- W2029063625 cites W181071460 @default.
- W2029063625 cites W1963922513 @default.
- W2029063625 cites W1969254836 @default.
- W2029063625 cites W1970821522 @default.
- W2029063625 cites W1976205221 @default.
- W2029063625 cites W1981977829 @default.
- W2029063625 cites W1982539837 @default.
- W2029063625 cites W1991985344 @default.
- W2029063625 cites W1992136696 @default.
- W2029063625 cites W2001082923 @default.
- W2029063625 cites W2010047996 @default.
- W2029063625 cites W2026897986 @default.
- W2029063625 cites W2036673466 @default.
- W2029063625 cites W2038587055 @default.
- W2029063625 cites W2039155143 @default.
- W2029063625 cites W2040565016 @default.
- W2029063625 cites W2041908551 @default.
- W2029063625 cites W2050591088 @default.
- W2029063625 cites W2051638257 @default.
- W2029063625 cites W2058928075 @default.
- W2029063625 cites W2060243074 @default.
- W2029063625 cites W2060947071 @default.
- W2029063625 cites W2064517416 @default.
- W2029063625 cites W2073223935 @default.
- W2029063625 cites W207384795 @default.
- W2029063625 cites W2075293518 @default.
- W2029063625 cites W2076033853 @default.
- W2029063625 cites W2076259686 @default.
- W2029063625 cites W2082045705 @default.
- W2029063625 cites W2085622340 @default.
- W2029063625 cites W2086856751 @default.
- W2029063625 cites W2093194212 @default.
- W2029063625 cites W2094335281 @default.
- W2029063625 cites W2114559268 @default.
- W2029063625 cites W2125048659 @default.
- W2029063625 cites W2149442475 @default.
- W2029063625 cites W2951800517 @default.
- W2029063625 cites W2952143463 @default.
- W2029063625 doi "https://doi.org/10.1016/j.apcata.2013.06.018" @default.
- W2029063625 hasPublicationYear "2013" @default.
- W2029063625 type Work @default.
- W2029063625 sameAs 2029063625 @default.
- W2029063625 citedByCount "7" @default.
- W2029063625 countsByYear W20290636252017 @default.
- W2029063625 countsByYear W20290636252018 @default.
- W2029063625 countsByYear W20290636252019 @default.
- W2029063625 countsByYear W20290636252020 @default.
- W2029063625 countsByYear W20290636252023 @default.
- W2029063625 crossrefType "journal-article" @default.
- W2029063625 hasAuthorship W2029063625A5031054717 @default.
- W2029063625 hasAuthorship W2029063625A5052246045 @default.
- W2029063625 hasConcept C127413603 @default.
- W2029063625 hasConcept C185592680 @default.
- W2029063625 hasConcept C2779679103 @default.
- W2029063625 hasConcept C55493867 @default.
- W2029063625 hasConcept C57600042 @default.
- W2029063625 hasConcept C76155785 @default.
- W2029063625 hasConceptScore W2029063625C127413603 @default.
- W2029063625 hasConceptScore W2029063625C185592680 @default.
- W2029063625 hasConceptScore W2029063625C2779679103 @default.
- W2029063625 hasConceptScore W2029063625C55493867 @default.
- W2029063625 hasConceptScore W2029063625C57600042 @default.
- W2029063625 hasConceptScore W2029063625C76155785 @default.
- W2029063625 hasLocation W20290636251 @default.
- W2029063625 hasOpenAccess W2029063625 @default.
- W2029063625 hasPrimaryLocation W20290636251 @default.
- W2029063625 hasRelatedWork W1971718390 @default.
- W2029063625 hasRelatedWork W1980531368 @default.
- W2029063625 hasRelatedWork W1984438765 @default.
- W2029063625 hasRelatedWork W2001703429 @default.
- W2029063625 hasRelatedWork W2052059215 @default.
- W2029063625 hasRelatedWork W2315723543 @default.
- W2029063625 hasRelatedWork W2533405060 @default.
- W2029063625 hasRelatedWork W2734999807 @default.
- W2029063625 hasRelatedWork W2952988122 @default.
- W2029063625 hasRelatedWork W2953080833 @default.
- W2029063625 hasVolume "466" @default.
- W2029063625 isParatext "false" @default.
- W2029063625 isRetracted "false" @default.
- W2029063625 magId "2029063625" @default.
- W2029063625 workType "article" @default.