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- W2029065312 abstract "Abstract Solid state interface reactions in high surface SiO 2 impregnated with lanthanum nitrate were studied at temperature 600–1200 °C with X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Fourier Transform Infrared spectroscopy (FTIR) and Raman spectroscopy. The results show that at 600–900 °C an amorphous, nanometer thick La O Si layer covering SiO 2 particles exists in the system. At higher temperatures the breakage of the layer into amorphous islands occurs and crystalline silicates with various structures are formed. La 6 [Si 4 O 13 ][SiO 4 ] 2 silicate forms at temperatures from 950 °C as the first, quasi two-dimensional phase, and then, at higher temperatures, A-La 2 Si 2 O 7 silicate occurs. Mechanism of formation of lanthanide silicates in high surface SiO 2 impregnated with Ln nitrates is proposed." @default.
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- W2029065312 date "2005-11-01" @default.
- W2029065312 modified "2023-10-18" @default.
- W2029065312 title "Interfacial reactions and silicate formation in high surface SiO2 impregnated with La nitrate" @default.
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- W2029065312 doi "https://doi.org/10.1016/j.solidstatesciences.2005.06.012" @default.
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