Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029084816> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2029084816 endingPage "268" @default.
- W2029084816 startingPage "263" @default.
- W2029084816 abstract "High-field 31P NMR spectroscopy and single crystal X-ray diffraction studies have been used to study the ring opening and nucleophilic substitution reactions of the λ3-cyclotriphosphazane [EtNPCl]3. The synthesis of the ring opened silicophosphonate [RSi(OH){OP(O)(H)(OH)}]2O (R = (2,6-iPr2C6H3)NSiMe3) (1) represents the first ever molecular silicophosphonate to be isolated bearing free reactive hydroxyl groups. The structure and conformation of the bulky aryloxide substituted λ3-cyclotriphosphazane derivative [EtNP(OAr)]3 (Ar = 2,6-iPr2C6H3) (2) has also been investigated. Interaction of 2 with transition metal precursor complexes leads to the isolation of phosphazane metal complexes with different mode of co-ordination of 2. Further, the reaction of Cp ★Ti(OAr)Cl2 (Ar = 2,6-(CH3)2C6H3OH) with O{SiPh2(OH)}2 gave the eight-membered trititanosiloxane [Cp ★Ti(Cl) (O(SiPh2O)2SiPh2O) (3). Siloxane chain expansion effects, presumed to be a consequence of ring strain, have been observed in the product. The presence of reactive Ti-Cl bond in 3 offers opportunities for its reaction chemistry to be explored." @default.
- W2029084816 created "2016-06-24" @default.
- W2029084816 creator A5025790792 @default.
- W2029084816 creator A5039836748 @default.
- W2029084816 creator A5045449975 @default.
- W2029084816 creator A5073107885 @default.
- W2029084816 date "2001-01-01" @default.
- W2029084816 modified "2023-10-03" @default.
- W2029084816 title "Metal Containing New Inorganic Ring Systems Based on Siloxane and Phosphazane Frameworks" @default.
- W2029084816 cites W1986592454 @default.
- W2029084816 cites W2013768143 @default.
- W2029084816 cites W2021543466 @default.
- W2029084816 cites W2085658214 @default.
- W2029084816 cites W2088019698 @default.
- W2029084816 cites W2108456755 @default.
- W2029084816 cites W2118948052 @default.
- W2029084816 cites W2949822551 @default.
- W2029084816 cites W2950547909 @default.
- W2029084816 cites W2952564019 @default.
- W2029084816 doi "https://doi.org/10.1080/10426500108546565" @default.
- W2029084816 hasPublicationYear "2001" @default.
- W2029084816 type Work @default.
- W2029084816 sameAs 2029084816 @default.
- W2029084816 citedByCount "2" @default.
- W2029084816 crossrefType "journal-article" @default.
- W2029084816 hasAuthorship W2029084816A5025790792 @default.
- W2029084816 hasAuthorship W2029084816A5039836748 @default.
- W2029084816 hasAuthorship W2029084816A5045449975 @default.
- W2029084816 hasAuthorship W2029084816A5073107885 @default.
- W2029084816 hasConcept C106159729 @default.
- W2029084816 hasConcept C106773901 @default.
- W2029084816 hasConcept C107111320 @default.
- W2029084816 hasConcept C111771559 @default.
- W2029084816 hasConcept C115624301 @default.
- W2029084816 hasConcept C135731615 @default.
- W2029084816 hasConcept C155647269 @default.
- W2029084816 hasConcept C161790260 @default.
- W2029084816 hasConcept C162324750 @default.
- W2029084816 hasConcept C178790620 @default.
- W2029084816 hasConcept C178907741 @default.
- W2029084816 hasConcept C185592680 @default.
- W2029084816 hasConcept C2776139660 @default.
- W2029084816 hasConcept C2780378348 @default.
- W2029084816 hasConcept C521977710 @default.
- W2029084816 hasConcept C544153396 @default.
- W2029084816 hasConcept C66974803 @default.
- W2029084816 hasConcept C71240020 @default.
- W2029084816 hasConcept C8010536 @default.
- W2029084816 hasConceptScore W2029084816C106159729 @default.
- W2029084816 hasConceptScore W2029084816C106773901 @default.
- W2029084816 hasConceptScore W2029084816C107111320 @default.
- W2029084816 hasConceptScore W2029084816C111771559 @default.
- W2029084816 hasConceptScore W2029084816C115624301 @default.
- W2029084816 hasConceptScore W2029084816C135731615 @default.
- W2029084816 hasConceptScore W2029084816C155647269 @default.
- W2029084816 hasConceptScore W2029084816C161790260 @default.
- W2029084816 hasConceptScore W2029084816C162324750 @default.
- W2029084816 hasConceptScore W2029084816C178790620 @default.
- W2029084816 hasConceptScore W2029084816C178907741 @default.
- W2029084816 hasConceptScore W2029084816C185592680 @default.
- W2029084816 hasConceptScore W2029084816C2776139660 @default.
- W2029084816 hasConceptScore W2029084816C2780378348 @default.
- W2029084816 hasConceptScore W2029084816C521977710 @default.
- W2029084816 hasConceptScore W2029084816C544153396 @default.
- W2029084816 hasConceptScore W2029084816C66974803 @default.
- W2029084816 hasConceptScore W2029084816C71240020 @default.
- W2029084816 hasConceptScore W2029084816C8010536 @default.
- W2029084816 hasIssue "1" @default.
- W2029084816 hasLocation W20290848161 @default.
- W2029084816 hasOpenAccess W2029084816 @default.
- W2029084816 hasPrimaryLocation W20290848161 @default.
- W2029084816 hasRelatedWork W1972899349 @default.
- W2029084816 hasRelatedWork W2009844083 @default.
- W2029084816 hasRelatedWork W2088690592 @default.
- W2029084816 hasRelatedWork W2162041534 @default.
- W2029084816 hasRelatedWork W2953039996 @default.
- W2029084816 hasRelatedWork W3164849189 @default.
- W2029084816 hasRelatedWork W4210882493 @default.
- W2029084816 hasRelatedWork W4239384447 @default.
- W2029084816 hasRelatedWork W4255845432 @default.
- W2029084816 hasRelatedWork W4285040813 @default.
- W2029084816 hasVolume "168" @default.
- W2029084816 isParatext "false" @default.
- W2029084816 isRetracted "false" @default.
- W2029084816 magId "2029084816" @default.
- W2029084816 workType "article" @default.