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- W2029111921 abstract "Abstract Methods are described for the preparation of highly enriched CF 3 Br and CF 3 Cl with 13 C content of 90% or higher in laboratory-scale quantities. These are based on isotope selective, vibrational photochemistry of CF 3 BrCl 2 and CF 3 ClBr 2 mixtures in two stages using a TEACO 2 laser. In CF 3 Br synthesis, 13 C selective dissociation is done in both the stages through a closed chemical cycle. However, 13 CF 3 Cl is obtained by photochemically burning 12 CF 3 Cl in a slightly enriched sample in the presence of Br 2 ." @default.
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- W2029111921 date "1994-10-01" @default.
- W2029111921 modified "2023-09-28" @default.
- W2029111921 title "TEACO2 laser-driven synthesis of 13CF3X (XBr or Cl)" @default.
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- W2029111921 doi "https://doi.org/10.1016/s1010-6030(94)80023-5" @default.
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