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• W2029119945 abstract "The microwave spectra have been recorded from 18.0 to 26.5 GHz for 12CH3GeH212C14N, 13CH3GeH212C14N, 12CH3GeH212C15N, 12CH3GeH213C14N, 12CH3GeD212C14N, and 12CD3GeH212C14N of the four naturally occurring isotopes of germane: 70Ge, 72Ge, 74Ge, and 76Ge. Only a-type transitions were observed and R-branch assignments have been made for all the isotopic species in the ground vibrational state from which the rotational constants were determined. From these data the complete structural parameters were determined to be r0(CME–Ge)=1.933±0.002 Å, r(Ge–CCN)=1.927±0.004 Å, r(C≡N)=1.155±0.004 Å, r(Ge–H)=1.521±0.001 Å, r(C–Hs)=1.092±0.005 Å, r(C–Ha)=1.092±0.005 Å, ∢CGeC=107.36°±0.60°, ∢HGeH=111.41°±0.04°, ∢HGeCMe=112.92°±0.08°, ∢HsCGe=109.5°±2.0°, and &lt;HaCGe=109.3°±0.8°, where all of the parameters are rs values except for the carbon–hydrogen distances and angles. The dipole moment components were determined from the Stark effect to be ‖μa‖=4.20±0.14, ‖μb‖=0.39±0.03, and ‖μt‖=4.22±0.14 D. From the microwave splitting method, the threefold barrier to internal rotation was determined to be 1148±23 cal/mol (402±8 cm−1). The infrared (3200 to 50 cm−1) and Raman spectra (3200 to 10 cm−1) of gaseous and solid CH3GeH2CN, CH3GeD2CN, and CD3GeH2CN have been obtained. Additionally, the Raman spectra of the liquids have been recorded and qualitative depolarization values have been obtained. A complete vibrational assignment is proposed based on infrared band contours, depolarization values, and isotopic shifts. These results are compared to similar quantities in some related molecules." @default.
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• W2029119945 date "1985-07-01" @default.
• W2029119945 modified "2023-10-17" @default.
• W2029119945 title "Spectra and structure of organogermanes. XXII. Microwave, infrared, and Raman spectra of methylgermyl cyanide" @default.
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• W2029119945 doi "https://doi.org/10.1063/1.449802" @default.
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