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- W2029121086 abstract "Abstract The influence of the substitution of H by D was investigated by means of the Mossbauer effect in the compounds FeC 2 O 4 O 4 ·2H 2 O and Fe(ClO 4 ) 2 ·6H 2 O. Isomer shifts δ and quadrupole splittings ϵ were measured between 90 and 300 K. An important isotope effect dependent on temperature was observed for the value of ϵ in oxalate. Only a slight difference for the value of δ could be determined in perchlorate. The well-known transition of the perchlorate takes place at temperatures which differ by 4 K for the deuterated and hydrogenated compounds." @default.
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- W2029121086 date "1974-12-01" @default.
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- W2029121086 title "Isotope effects measured by mössbauer spectrometry in ferrous oxalate and perchlorate" @default.
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- W2029121086 doi "https://doi.org/10.1016/0009-2614(74)85124-9" @default.
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