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- W2029128740 abstract "The photoinduced absorption and bleaching of trans -(CH) x and trans -(CD) x in the nanosecond time region were investigated for the first time by time-resolved absorption spectroscopy. The transient absorption near the band gap and the bleaching of the interband transition were observed for both trans -(CH) x and trans -(CD) x . The absorption near the band gap saturated at Δ A / A 0 ∼0.01. The decay of transient absorption at 4 K was fitted to (erf[(t/tau)^{-1/2}]) with τ=144±15 ns for trans -(CD) x and τ=305±27 ns for trans -(CD) x . When the temperature is increased, the decay kinetics are given by the same function with shorter time constants, τ=32±6 ns for trans -(CH) x and τ=40±6 ns for trans -(CD) x at 290 K. When the trans content in cis -rich film decreased, the time constant became longer. The decay kinetics is interpreted by interchain recombination of photoinduced polaron pairs." @default.
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- W2029128740 date "1987-02-15" @default.
- W2029128740 modified "2023-10-16" @default.
- W2029128740 title "Nanosecond Time-Resolved Photoinduced Absorption of<i>trans</i>-Polyacetylene" @default.
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- W2029128740 doi "https://doi.org/10.1143/jpsj.56.768" @default.
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