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- W2029132697 abstract "The initial stages of the process of heterogeneous nucleation in the electrodeposition of mercury on a platinum single crystal electrode are studied in detail. It is found that at constant overvoltage (equivalent to the supersaturation in vapour phase) the rate of nucleation increases steadily with time, reaching gradually a time-independent value. This is in accordance with some basic concepts of the phenomenological theory of nucleation which predicts transient effects due to the necessity to build up a stationary distribution of submicroscopical clusters of the new phase. The experimental curves giving the number of nuclei as a function of time can be correlated quantitatively with the theory. Induction times τ ranging from 20 μsec to 600 μsec, depending on the overpotential applied, as well as steady state nucleation rates are evaluated from the experimental data. Two alternatives are tentatively discussed to account for the absolute values of the time lags: growth of mercury clusters by surface diffusion of adatoms and growth by direct discharge of ions from the electrolytic solution. The second path provides a more reasonable though still qualitative explanation of the experimental results. The steady state nucleation rates are related formally to the supersaturation as required by the classical theory of nucleation." @default.
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- W2029132697 date "1968-01-01" @default.
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- W2029132697 title "Transient nucleation in electrodeposition of mercury" @default.
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- W2029132697 doi "https://doi.org/10.1016/0022-0248(68)90194-2" @default.
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