Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029133782> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2029133782 endingPage "894" @default.
- W2029133782 startingPage "889" @default.
- W2029133782 abstract "The oxidative addition of dihydrogen to the [RhH(SnCl3)5]3–/PR3 system (PR3 = PPh3, PEtPh2, PEt3) leads to the formation of previously unknown dihydride complexes, the 1H-NMR spectra of which have been studied by means of the ParaHydrogen Induced Polarization (PHIP) method. The composition of the resulting complexes crucially depends on the type of the added phosphane. With PEt3 as the phosphane and acetonitrile as the solvent, a complex with a SnCl2L ligand (L = CD3CN) can be detected. All systems examined catalyze the hydrogenation of phenylacetylene. During these reactions, both the 1H-NMR resonances of the dihydride complexes and those of styrene, the hydrogenation product of phenylacetylene, can be detected simultaneously. In the case of SnBr3 ligands, hydrogen addition in the presence of phosphanes leads to similar dihydride complexes, which were also identified via 1H-NMR spectroscopy. Furthermore, a mixed complex of the structure [Rh(SnBr3)nBr6–n]3– has been isolated." @default.
- W2029133782 created "2016-06-24" @default.
- W2029133782 creator A5039859572 @default.
- W2029133782 creator A5046633648 @default.
- W2029133782 creator A5049710711 @default.
- W2029133782 creator A5054360372 @default.
- W2029133782 date "2000-05-01" @default.
- W2029133782 modified "2023-09-23" @default.
- W2029133782 title "In situ NMR Detection of Dihydrides in the Systems [RhH(SnCl3)5]3–/Tertiary Phosphanes/Parahydrogen" @default.
- W2029133782 cites W1963673802 @default.
- W2029133782 cites W1978014013 @default.
- W2029133782 cites W2008478285 @default.
- W2029133782 cites W2014339021 @default.
- W2029133782 cites W2021159766 @default.
- W2029133782 cites W2026614021 @default.
- W2029133782 cites W2092455780 @default.
- W2029133782 cites W2156432419 @default.
- W2029133782 cites W2329743819 @default.
- W2029133782 cites W2488902946 @default.
- W2029133782 doi "https://doi.org/10.1002/(sici)1099-0682(200005)2000:5<889::aid-ejic889>3.0.co;2-o" @default.
- W2029133782 hasPublicationYear "2000" @default.
- W2029133782 type Work @default.
- W2029133782 sameAs 2029133782 @default.
- W2029133782 citedByCount "6" @default.
- W2029133782 countsByYear W20291337822012 @default.
- W2029133782 crossrefType "journal-article" @default.
- W2029133782 hasAuthorship W2029133782A5039859572 @default.
- W2029133782 hasAuthorship W2029133782A5046633648 @default.
- W2029133782 hasAuthorship W2029133782A5049710711 @default.
- W2029133782 hasAuthorship W2029133782A5054360372 @default.
- W2029133782 hasConcept C103319777 @default.
- W2029133782 hasConcept C116569031 @default.
- W2029133782 hasConcept C155647269 @default.
- W2029133782 hasConcept C15920480 @default.
- W2029133782 hasConcept C161790260 @default.
- W2029133782 hasConcept C170493617 @default.
- W2029133782 hasConcept C178790620 @default.
- W2029133782 hasConcept C185592680 @default.
- W2029133782 hasConcept C19449701 @default.
- W2029133782 hasConcept C2777463227 @default.
- W2029133782 hasConcept C2777566558 @default.
- W2029133782 hasConcept C2777961443 @default.
- W2029133782 hasConcept C2778545935 @default.
- W2029133782 hasConcept C2780471494 @default.
- W2029133782 hasConcept C512968161 @default.
- W2029133782 hasConcept C521977710 @default.
- W2029133782 hasConcept C55493867 @default.
- W2029133782 hasConcept C66974803 @default.
- W2029133782 hasConcept C70038680 @default.
- W2029133782 hasConcept C71240020 @default.
- W2029133782 hasConcept C75473681 @default.
- W2029133782 hasConceptScore W2029133782C103319777 @default.
- W2029133782 hasConceptScore W2029133782C116569031 @default.
- W2029133782 hasConceptScore W2029133782C155647269 @default.
- W2029133782 hasConceptScore W2029133782C15920480 @default.
- W2029133782 hasConceptScore W2029133782C161790260 @default.
- W2029133782 hasConceptScore W2029133782C170493617 @default.
- W2029133782 hasConceptScore W2029133782C178790620 @default.
- W2029133782 hasConceptScore W2029133782C185592680 @default.
- W2029133782 hasConceptScore W2029133782C19449701 @default.
- W2029133782 hasConceptScore W2029133782C2777463227 @default.
- W2029133782 hasConceptScore W2029133782C2777566558 @default.
- W2029133782 hasConceptScore W2029133782C2777961443 @default.
- W2029133782 hasConceptScore W2029133782C2778545935 @default.
- W2029133782 hasConceptScore W2029133782C2780471494 @default.
- W2029133782 hasConceptScore W2029133782C512968161 @default.
- W2029133782 hasConceptScore W2029133782C521977710 @default.
- W2029133782 hasConceptScore W2029133782C55493867 @default.
- W2029133782 hasConceptScore W2029133782C66974803 @default.
- W2029133782 hasConceptScore W2029133782C70038680 @default.
- W2029133782 hasConceptScore W2029133782C71240020 @default.
- W2029133782 hasConceptScore W2029133782C75473681 @default.
- W2029133782 hasIssue "5" @default.
- W2029133782 hasLocation W20291337821 @default.
- W2029133782 hasOpenAccess W2029133782 @default.
- W2029133782 hasPrimaryLocation W20291337821 @default.
- W2029133782 hasRelatedWork W1248821753 @default.
- W2029133782 hasRelatedWork W1968841183 @default.
- W2029133782 hasRelatedWork W1976022058 @default.
- W2029133782 hasRelatedWork W2004599238 @default.
- W2029133782 hasRelatedWork W2030441499 @default.
- W2029133782 hasRelatedWork W2034025093 @default.
- W2029133782 hasRelatedWork W2051981582 @default.
- W2029133782 hasRelatedWork W2065915336 @default.
- W2029133782 hasRelatedWork W2114257229 @default.
- W2029133782 hasRelatedWork W2334469789 @default.
- W2029133782 hasVolume "2000" @default.
- W2029133782 isParatext "false" @default.
- W2029133782 isRetracted "false" @default.
- W2029133782 magId "2029133782" @default.
- W2029133782 workType "article" @default.