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• W2029133925 abstract "The calixarene phosphites L1–L4 were obtained in high yield through reaction of PCl3/NEt3 with the monofunctionalised cone-calixarenes p-tert-butylcalix[4]arene(OH)3OR, in which the R substituents bear an oxygen donor ligand [R = CH2P(O)Ph2 (L1), CH2CO2Et (L2), CH2C(O)NEt2 (L3), CH2CH2OMe (L4)]. The calixarene core of the four ligands adopts a cone conformation and, hence, the phosphites become potential P,O-chelating systems. Phosphite L1 is remarkably stable towards aqueous NaOH, but the presence of slightly acidic water results in phosphonate formation. Slow oxidation of L1 in air afforded the corresponding mixed phosphine oxide–phosphate. In the complexes [RuCl2(p-cymene)L1], [cis-PtCl2(L1)2] (9), trans-[PdCl2(L1)2], [Pd(8-mq)Cl(Ln)] (8-mqH = 8-methylquinoline, n = 1–3), [Pd(dmba)Cl(L1)] (dmbaH = N,N-dimethylbenzylamine), [Pd(η3-C4H7)Cl(L2)], [Rh(acac)(CO)Ln] (n = 1–3) and [RhCl(CO)(L1)2], the phosphites behave as a monodentate phosphorus donor ligands. Owing to their steric crowding, the two cis-disposed ligands of complex 9 cannot freely rotate about their coordination axis. In the solid state, the calixarene backbones of complex 9 display a so-called ‘up-up-out-up’ conformation. Chelating phosphite behaviour was found in the cationic complexes [Pd(8-mq)Ln]BF4 (n = 1–3). In solution, the large, chelating P,O-loop of the latter complexes swings from one side of the metal plane to the other, the dynamics possibly being facilitated by the flexibility of the calixarene backbone. The four oxo-functionalised phosphites were tested as catalysts for 1-octene hydroformylation. The observed reaction rates lie in the range reported for other medium-bulky phosphites. Furthermore, the hydroformylation rate decreases as the donor strength of the side group increases, suggesting binding of the O-donor during catalysis. The L/B ratios lie in the range 1.4–3.6, the highest linear aldehyde selectivity being observed with the phosphite ester L3." @default.
• W2029133925 created "2016-06-24" @default.
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• W2029133925 date "2002-10-22" @default.
• W2029133925 modified "2023-10-14" @default.
• W2029133925 title "Heterofunctionalised phosphites built on a calix[4]arene scaffold and their use in 1-octene hydroformylation. Formation of 12-membered P,O-chelate rings" @default.
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• W2029133925 doi "https://doi.org/10.1039/b204604k" @default.
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