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- W2029142023 abstract "Abstract Monomeric serine can be trapped in low temperature argon matrices in different conformers, which can be classified in three groups ( A , B , C ) accordingly to the main intramolecular interaction they exhibit: A (OH A ⋯N hydrogen bond), B (OH C ⋯N) and C (OH A ⋯O ) (subscripts A and C stand for alcohol and carboxylic group, respectively). The OH C ⋯N intramolecular interaction found in B -type conformers is considerably stronger than both the OH A ⋯N and OH A ⋯O hydrogen bonds, and leads to reduce the abundance of B -type form relatively to A and C forms at high temperatures due to entropy effects. When submitted to UV irradiation ( λ >200 nm), the main observed photoprocess is decarboxylation, leading to production of CO 2 and ethanolamine. A less important photochemical process is also observed, where the compound undergoes decarbonylation, with formation of CO, H 2 O and acetamide. The two observed photoprocesses were found to be dependent on the conformation assumed by the reactant molecule, with A - and C -type conformers of serine undergoing decarboxylation and B -type conformers decarbonylation." @default.
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- W2029142023 date "2006-04-01" @default.
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- W2029142023 title "Entropy effects in conformational distribution and conformationally dependent UV-induced photolysis of serine monomer isolated in solid argon" @default.
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