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- W2029145812 abstract "Abstract Lithiated 1,3-dithianes react with trialkyltin or triphenyltin chlorides to form the corresponding 1,3-dithian-2-yltin compounds. The dithiane C(2)Sn bond in the trialkyltin or triphenyltin compounds is selectively cleaved by iodine, with formation of 1,3-dithian-2-ylium triiodides which can be transformed into the corresponding tetrafluoroborate salts. The 1 H and 13 C NMR data are consistent with the salt like structures. The ambident nature of β-styryl derivatives is discussed. Preferential cleavage of the C(2)Sn bond in the stannyl derivatives is evident in the mass spectra." @default.
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- W2029145812 date "1986-04-01" @default.
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- W2029145812 title "Organotin derivatives in the umpolung of 1,3-dithian-2-ylides to 1,3-dithian-2-ylium salts" @default.
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- W2029145812 doi "https://doi.org/10.1016/0022-328x(86)80130-9" @default.
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