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- W2029146439 abstract "Abstract The 39K quadrupole coupling tensors and chemical-shift tensors have been determined in KSCN and the SCN and NH4 nitrogen quadrupole coupling tensors have been determined in NH4SCN as a function of temperature. The results for KSCN show, that the symmetry of the paraelectric phase is broken on the quadrupole-coupling time scale but not on the chemical-shift time scale, implying that the characteristic time for structural fluctuations is between 10−5 sec and 10−2 sec. The high temperature phase of NH4SCN is dynamically disordered with the hydrogen-bonded NH4 ions moving between 4 equivalent off-center sites. In the orthorhombic phase two of the 4 NH4-sites freeze out, so that this phase is partially ordered." @default.
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- W2029146439 date "1992-01-01" @default.
- W2029146439 modified "2023-10-01" @default.
- W2029146439 title "Microscopic model for the structural phase transitions in NH4SCN and KSCN" @default.
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- W2029146439 doi "https://doi.org/10.1080/00150199208017077" @default.
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