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• W2029151657 abstract "The preparations and X-ray crystal structures of the Ru(II) aminophosphine complexes trans, cis-[RuCl2(H(Bz)NCH2CH2PPh2-N,P)2] (1), trans, cis-[RuCl2(H2NCH2CH2PPh2-N,P)2] (3) and [(η6-C6H6)Ru(PPh2CH2CH2NMe2-N,P)Cl][PF6] (5) are described. Complexes 1 and 3 are octahedral and contain a marked distortion of the Cl-Ru-Cl axis from linearity. Complex 3 undergoes facile chelate ring-opening in DMSO and CH3CN solutions to give complexes containing one chelated aminophosphine ligand and one pendant ligand coordinated only through P. The X-ray structure of trans, cis-[RuCl2(DMSO-S)2(H2NCH2CH2P(O)Ph2-N,O)] (4) containing an oxidised aminophosphine ligand is also reported." @default.
• W2029151657 created "2016-06-24" @default.
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• W2029151657 date "2002-11-01" @default.
• W2029151657 modified "2023-10-12" @default.
• W2029151657 title "Chelate ring-opening aminophosphine complexes of ruthenium(II)" @default.
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• W2029151657 doi "https://doi.org/10.1016/s0020-1693(02)01133-7" @default.
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