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- W2029156631 abstract "Solvothermal reactions of mixed ligands H3BTC and macrocyclic oxamide complexes (ML, M = Cu, Ni) with M(ClO4)2·6H2O (M = Co, Zn, Ni and Cd) afford six new complexes, including [M′4(BTC)2(ML)2(OH)2(H2O)2]·2H2O (M′ = Co, M = Ni, for (1); M′ = Zn, M = Ni, for (2); M′ = Zn, M = Cu, for (3)), [Ni3(BTC)2(NiL)2(H2O)6]·2CH3OH·2H2O (4), [Cd4(BTC)2(HBTC)(NiL)4(H2O)]·3H2O (5) and [Cd(HBTC)(CuL)]·H2O (6) (ML, H2L = 2, 3-dioxo-5, 6, 14, 15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien; H3BTC = 1,3,5-benzenetricarboxylic acid). Complexes 1–3 consist of a 2D layer framework formed by the linkage of M(II)(M = Ni, Cu) and M′4 (M′ = Co, Zn) clustervia the oxamide and BTC3− bridges and display a (3,6)-connected network with a (43)2(46.66.83) topology. The structure of 4 consists of pentanuclear [NiII5] units and arranges in a 1D cluster chain. Complex 5 exhibits a 2D layered structure characterized by 3,4,3-connected (4.62)3(4.63.82)(42.63.8)(42.6) topology. Complex 6 possesses a 3D network with sra topology. The magnetic properties of complexes 1 and 4 were investigated." @default.
- W2029156631 created "2016-06-24" @default.
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- W2029156631 date "2011-01-01" @default.
- W2029156631 modified "2023-09-23" @default.
- W2029156631 title "Coordination polymers of macrocyclic oxamide with 1,3,5-benzenetricarboxylate: syntheses, crystal structures and magnetic properties" @default.
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- W2029156631 doi "https://doi.org/10.1039/c0dt01584a" @default.
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