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- W2029163609 abstract "The synthesis of complexes 2 [W(CC6H4(CCC6H4NH2-4)-4)Cl(CO)2(dppe)], and 4 [W(CC6H4(CCC6H4(CCC6H2iPr2-3,5-NHCHO-4)-4)-4)Cl(CO)2(dppe)], was achieved by Pd(II) catalyzed cross-coupling reactions of complex 1 [W(CC6H4I-4)Cl(CO)2(dppe)], with the respective aromatic acetylenes. Formylation of complex 2 with acetic formic anhydride affords the formamide 3 [W(CC6H4(CCC6H4NHCHO-4)-4)Cl(CO)2(dppe)]. The isocyanide derivatives 5 [W(CC6H4(CCC6H4NC-4)-4)Cl(CO)2(dppe)], and 6 [W(CC6H4(CCC6H4(CCC6H2iPr2-3,5-NC-4)-4)-4)Cl(CO)2(dppe)], were obtained by dehydration of complexes 3 and 4 with triphosgene/NEt3." @default.
- W2029163609 created "2016-06-24" @default.
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- W2029163609 date "1999-04-01" @default.
- W2029163609 modified "2023-10-17" @default.
- W2029163609 title "Unsaturated alkylidyne ligands bearing a terminal isocyanide functionality and intervening ethynylbenzene groups" @default.
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- W2029163609 doi "https://doi.org/10.1016/s0022-328x(98)01045-6" @default.
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