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• W2029164545 endingPage "5809" @default.
• W2029164545 startingPage "5806" @default.
• W2029164545 abstract "We present a general strategy for incorporating organocatalytic moieties into metal−organic frameworks (MOFs). The organocatalytic units are protected by a thermolabile protecting group during MOF synthesis and then unveiled by a simple postsynthetic heating step. The strategy is exemplified using a thermolabile tert-butoxycarbonyl (Boc) protecting group for a proline moiety, the removal of which endows the resulting cubic zinc(II) IRMOF with catalytic activity for asymmetric aldol reactions. The bulky Boc groups also prevent framework interpenetration, producing open MOFs that can admit relatively large substrates." @default.
• W2029164545 created "2016-06-24" @default.
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• W2029164545 creator A5028089575 @default.
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• W2029164545 date "2011-03-28" @default.
• W2029164545 modified "2023-10-03" @default.
• W2029164545 title "A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks" @default.
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• W2029164545 doi "https://doi.org/10.1021/ja202223d" @default.
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