FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2029172878> ?p ?o ?g. }

• W2029172878 endingPage "2581" @default.
• W2029172878 startingPage "2573" @default.
• W2029172878 abstract "Abstract A concept, complementary to that of hard and soft acid–base interactions (HSAB‐dominant chemisorption) and consistent with dominant physisorption to a semiconductor interface, is presented. We create a matrix of sensitivities and interactions with several basic gases. The concept, based on the reversible interaction of hard‐acid surfaces with soft bases, hard‐base surfaces with soft acids, or vice versa, corresponds 1) to the inverse of the HSAB concept and 2) to the selection of a combination of semiconductor interface and analyte materials, which can be used to direct a physisorbed vs chemisorbed interaction. The technology, implemented on nanopore coated porous silicon micropores, results in the coupling of acid–base chemistry with the depletion or enhancement of majority carriers in an extrinsic semiconductor. Using the inverse‐HSAB (IHSAB) concept, significant and predictable changes in interface sensitivity for a variety of gases can be implemented. Nanostructured metal oxide particle depositions provide selectivity and complement a highly efficient electrical contact to a porous silicon nanopore covered microporous interface. The application of small quantities (much less than a monolayer) of nanostructured metals, metal oxides, and catalysts which focus the physisorbtive and chemisorbtive interactions of the interface, can be made to create a range of notably higher sensitivities for reversible physisorption. This is exemplified by an approach to reversible, sensitive, and selective interface responses. Nanostructured metal oxides developed from electroless gold (Au x O), tin (SnO 2 ), copper (Cu x O), and nickel (NiO) depositions, nanoalumina, and nanotitania are used to demonstrate the IHSAB concept and provide for the detection of gases, including NH 3 , PH 3 , CO, NO, and H 2 S, in an array‐based format to the sub‐ppm level." @default.
• W2029172878 created "2016-06-24" @default.
• W2029172878 creator A5013107802 @default.
• W2029172878 creator A5084766011 @default.
• W2029172878 date "2010-08-16" @default.
• W2029172878 modified "2023-10-16" @default.
• W2029172878 title "Nanostructure-Directed Physisorption vs Chemisorption at Semiconductor Interfaces: The Inverse of the HSAB Concept" @default.
• W2029172878 cites W1965325929 @default.
• W2029172878 cites W1971726669 @default.
• W2029172878 cites W1975857552 @default.
• W2029172878 cites W1977484451 @default.
• W2029172878 cites W1984267986 @default.
• W2029172878 cites W1988865579 @default.
• W2029172878 cites W1990147235 @default.
• W2029172878 cites W1994780527 @default.
• W2029172878 cites W2002517724 @default.
• W2029172878 cites W2003454445 @default.
• W2029172878 cites W2005877813 @default.
• W2029172878 cites W2008708918 @default.
• W2029172878 cites W2009458392 @default.
• W2029172878 cites W2010807430 @default.
• W2029172878 cites W2020480574 @default.
• W2029172878 cites W2028856433 @default.
• W2029172878 cites W2030082437 @default.
• W2029172878 cites W2030257254 @default.
• W2029172878 cites W2031240265 @default.
• W2029172878 cites W2032664354 @default.
• W2029172878 cites W2044202126 @default.
• W2029172878 cites W2051116798 @default.
• W2029172878 cites W2060120274 @default.
• W2029172878 cites W2068559689 @default.
• W2029172878 cites W2077796804 @default.
• W2029172878 cites W2078462300 @default.
• W2029172878 cites W2080976563 @default.
• W2029172878 cites W2092321474 @default.
• W2029172878 cites W2095269805 @default.
• W2029172878 cites W2101958915 @default.
• W2029172878 cites W2123509557 @default.
• W2029172878 cites W2161763022 @default.
• W2029172878 cites W2503005323 @default.
• W2029172878 cites W2912207476 @default.
• W2029172878 cites W3021000211 @default.
• W2029172878 doi "https://doi.org/10.1002/cphc.201000245" @default.
• W2029172878 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20648514" @default.
• W2029172878 hasPublicationYear "2010" @default.
• W2029172878 type Work @default.
• W2029172878 sameAs 2029172878 @default.
• W2029172878 citedByCount "33" @default.
• W2029172878 countsByYear W20291728782012 @default.
• W2029172878 countsByYear W20291728782013 @default.
• W2029172878 countsByYear W20291728782014 @default.
• W2029172878 countsByYear W20291728782015 @default.
• W2029172878 countsByYear W20291728782016 @default.
• W2029172878 countsByYear W20291728782018 @default.
• W2029172878 countsByYear W20291728782019 @default.
• W2029172878 countsByYear W20291728782020 @default.
• W2029172878 countsByYear W20291728782021 @default.
• W2029172878 countsByYear W20291728782022 @default.
• W2029172878 crossrefType "journal-article" @default.
• W2029172878 hasAuthorship W2029172878A5013107802 @default.
• W2029172878 hasAuthorship W2029172878A5084766011 @default.
• W2029172878 hasConcept C108225325 @default.
• W2029172878 hasConcept C150394285 @default.
• W2029172878 hasConcept C171250308 @default.
• W2029172878 hasConcept C178790620 @default.
• W2029172878 hasConcept C179104552 @default.
• W2029172878 hasConcept C185592680 @default.
• W2029172878 hasConcept C186187911 @default.
• W2029172878 hasConcept C192562407 @default.
• W2029172878 hasConcept C2776685891 @default.
• W2029172878 hasConcept C2780050857 @default.
• W2029172878 hasConcept C33790079 @default.
• W2029172878 hasConcept C47548479 @default.
• W2029172878 hasConcept C49040817 @default.
• W2029172878 hasConcept C544956773 @default.
• W2029172878 hasConceptScore W2029172878C108225325 @default.
• W2029172878 hasConceptScore W2029172878C150394285 @default.
• W2029172878 hasConceptScore W2029172878C171250308 @default.
• W2029172878 hasConceptScore W2029172878C178790620 @default.
• W2029172878 hasConceptScore W2029172878C179104552 @default.
• W2029172878 hasConceptScore W2029172878C185592680 @default.
• W2029172878 hasConceptScore W2029172878C186187911 @default.
• W2029172878 hasConceptScore W2029172878C192562407 @default.
• W2029172878 hasConceptScore W2029172878C2776685891 @default.
• W2029172878 hasConceptScore W2029172878C2780050857 @default.
• W2029172878 hasConceptScore W2029172878C33790079 @default.
• W2029172878 hasConceptScore W2029172878C47548479 @default.
• W2029172878 hasConceptScore W2029172878C49040817 @default.
• W2029172878 hasConceptScore W2029172878C544956773 @default.
• W2029172878 hasIssue "12" @default.
• W2029172878 hasLocation W20291728781 @default.
• W2029172878 hasLocation W20291728782 @default.
• W2029172878 hasOpenAccess W2029172878 @default.
• W2029172878 hasPrimaryLocation W20291728781 @default.
• W2029172878 hasRelatedWork W2015773381 @default.
• W2029172878 hasRelatedWork W2035861595 @default.
• W2029172878 hasRelatedWork W2044792071 @default.
• W2029172878 hasRelatedWork W2084843316 @default.

• next