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- W2029201259 abstract "Die Reaktion von Fe2(CO)9 mit PCl3 bzw. AsCl3 führt zu Komplexen 1, 2, in denen eine Fe2(CO)8-Gruppe und ein Fe2(CO)6(η2-Cl)-Fragment über Phosphor bzw. Arsen als Spirozentren zu vierkernigen Clustern Fe2(CO)8XFe2(CO)6Cl mit X = P, As verknüpft sind. Die spektroskopischen Eigenschaften und der röntgenographisch ermittelte Bau dieser Verbindungen werden beschrieben. Phosphorus and Arsenic Atoms as Spiro Centers within Iron Clusters Reaction of Fe2(CO)9 with PCl3 or AsCl3 leads to complexes which contain an Fe2(CO)8 group and an Fe2(CO)6(η2-Cl) moiety joined by phosphorus or arsenic, respectively, with these atoms acting as spiro centers. The spectroscopic properties of the resulting clusters Fe2(CO)8XFe2(CO)6Cl (X = P, As) as well as their structures as determined by X-ray methods are described." @default.
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- W2029201259 date "1982-06-01" @default.
- W2029201259 modified "2023-09-28" @default.
- W2029201259 title "Phosphor‐ und Arsenatome als Spirozentren in Eisenclustern" @default.
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- W2029201259 doi "https://doi.org/10.1002/cber.19821150605" @default.
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