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• W2029202487 endingPage "1602" @default.
• W2029202487 startingPage "1589" @default.
• W2029202487 abstract "Recently reported experimental and theoretical studies of nanofluidic nonlinear devices, such as bipolar and unipolar ionic diodes, have yet to answer the question about the possibility of their further miniaturization. In this Article, we theoretically investigate the effects of size reduction, applied bias, and solution ionic strength in such devices. We compare the numerical solutions of the Poisson, Nernst-Planck (PNP), and Navier-Stokes (NS) equations with their one-dimensional, analytical approximations. We demonstrate that the contribution of electroosmosis is insignificant and find analytical approximations to PNP for bipolar and unipolar diodes that are in good agreement with numerical 3D solutions. We identify the minimal dimensions for such diodes that demonstrate ion current rectification behavior and demonstrate the importance of the edge effect in very short diodes." @default.
• W2029202487 created "2016-06-24" @default.
• W2029202487 creator A5015100789 @default.
• W2029202487 creator A5018422867 @default.
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• W2029202487 date "2008-07-22" @default.
• W2029202487 modified "2023-10-16" @default.
• W2029202487 title "Nanofluidic Ionic Diodes. Comparison of Analytical and Numerical Solutions" @default.
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• W2029202487 doi "https://doi.org/10.1021/nn800306u" @default.
• W2029202487 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19206361" @default.
• W2029202487 hasPublicationYear "2008" @default.
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