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- W2029220612 endingPage "1988" @default.
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- W2029220612 abstract "The molecular structure of silyl acetate has been determined in the gas phase by electron diffraction and in the crystalline state by X-ray diffraction. The Si–O bond length is 1.685(3)Å in the gas and 1.696(4)Å in the solid. In both phases the heavy-atom skeleton is almost planar with the Si–O and CO bonds arranged cis to one another giving intramolecular Si ⋯ O (carbonyl) distances of 2.795(14)Å(gas) and 2.832(4)Å(solid). The crystal structure is distinguished by having unusually short Si ⋯ O (carbonyl) intermolecular contacts of length 2.721 (4)Å; these interactions exhibit the stereospecificity associated with secondary bonds. Solid methyl acetate, studied to provide a reference structure, has no short intermolecular contacts." @default.
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- W2029220612 date "1981-01-01" @default.
- W2029220612 modified "2023-10-03" @default.
- W2029220612 title "Crystal structures of silyl acetate at 150 K and methyl acetate at 145 K, and the molecular structure of silyl acetate in the gas phase" @default.
- W2029220612 doi "https://doi.org/10.1039/dt9810001988" @default.
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