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- W2029222353 abstract "We present the inverse photoemission spectra of compounds which unambiguously display either homogeneous or inhomogeneous mixed valence, TmSe, and oxidized SmS. The spectra show two $4f$ peaks, ${4f}^{n}$ and ${4f}^{n+1}$, arising from the ${4f}^{nensuremath{-}1}$ and ${4f}^{n}$ ground-state configurations. These data, along with inverse photoemission spectra on clean SmS, show that the $4f$ inner potential well is stable enough to contain one more $4f$ electron than in the divalent, atomic ground state. The valence deduced from the TmSe bremsstrahlung isochromat spectrum agrees well with that obtained from other spectroscopic studies." @default.
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- W2029222353 date "1984-01-15" @default.
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- W2029222353 title "Inverse photoemission of mixed-valence compounds and4finner-well stability" @default.
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- W2029222353 doi "https://doi.org/10.1103/physrevb.29.589" @default.
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