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- W2029230225 abstract "Fluoroalkenes of general structure R−CFCF−CF3 (2a, R = cyclopentyl and 2b, R = cyclohexyl), prepared in high yield in two steps from hexafluoropropene and the appropriate cycloalkane, react with oxygen, carbon, and hydrogen nucleophiles to give R−CXCF−CF3 derivatives (X = H, OR, R, Ar). Reaction of fluoroalkenes 2a and 2b with allylic alkoxides gave products arising from Claisen rearrangement, providing access to keto-alkenes bearing >CFCF3 units in mid-aliphatic chain positions." @default.
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- W2029230225 date "2001-06-19" @default.
- W2029230225 modified "2023-10-16" @default.
- W2029230225 title "Nucleophilic Substitution and Claisen Rearrangement Reactions of Model Fluoroalkenes of General Structure R−CFCF−CF<sub>3</sub>" @default.
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- W2029230225 doi "https://doi.org/10.1021/jo0103118" @default.
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