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- W2029239103 abstract "Abstract A novel fullerene derivative with an N -hexylphenothiazine moiety, PTZ-C 60, was synthesized and characterized. The new synthesized fullerene showed good solubility in common organic solvents such as toluene, chlorobenzene and 1, 2 dichlorobenzene. The synthetic product PTZ-C 60 was characterized by 1 H and 13 C NMR, FT-IR and UV–vis spectroscopy. Photovoltaic devices were fabricated using the new fullerene derivative as the electron acceptor and P3HT as the electron donor. The configuration of the device was as follows: ITO/PEDOT:PSS/active layer/LiF/Al. The weight ratios of the electron donor to the acceptor in the active layer were 1:0.5, 1:0.7, and 1:1. The open-circuit voltage ( V oc ) of the fabricated devices was found to be higher than that of devices based on C 60 because the LUMO energy level of the new fullerene derivative was higher than that of C 60 . Further, the power conversion efficiency (PCE) of these devices was observed to be high when annealing was carried out at 150 °C for 5 min and the thickness of the active layer was 80 nm. The maximum V oc , short-circuit current density, and PCE of the best device were 0.608 V, 4.393 mA/cm 2 , and 1.29%, respectively." @default.
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- W2029239103 date "2011-04-01" @default.
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- W2029239103 title "Synthesis and characterization of a novel fullerene derivative for use in organic solar cells" @default.
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- W2029239103 doi "https://doi.org/10.1016/j.solmat.2010.12.052" @default.
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