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- W2029248906 abstract "The hydrostannation of 2-vinyl-4,4,6-trimethyl-1,3,2-dioxaborinane (VTDB) with trimethyl-, triethyl-, tripropyl-, tributyl-, and triphenyltin hydrides has been studied. The hydrostannation reactions, in all the cases studied, provided adducts with the organotin moiety at the β-carbon position; there was no indication of adducts with the organotin moiety at the α-carbon position. The reaction rate of tributyltin hydride with VTDB was accelerated by azobis(isobutyronitrile) (AIBN), retarded by galvinoxyl radical, and unaffected by change in solvent polarity. These observations confirm a free radical process for the hydrostannation of VTDB with triorganotin hydrides." @default.
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- W2029248906 date "1972-09-01" @default.
- W2029248906 modified "2023-09-23" @default.
- W2029248906 title "Hydrostannation of 2-vinyl-4,4,6-trimethyl-1,3,2-dioxaborinane" @default.
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- W2029248906 doi "https://doi.org/10.1016/s0022-328x(00)90084-6" @default.
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