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- W2029253651 abstract "(±)-(2Z,4E)-α-Ionylideneacetic acid (2) was enantioselectively oxidized to (−)-(l′S)-(2Z,4E)-4′-hydroxy-α-ionylideneacetic acid (3), (+)-(1′R)-(2Z,4E)-4′-oxo-α-ionylideneacetic acid (4) and (+)-abscisic acid (ABA) (1) by Cercospora cruenta IFO 6164, which can produce (+)-ABA and (+)-4′-oxo-α-acid 4. This metabolism was confirmed by the incorporation of radioactivity from (±)-(2-14C)-(2Z,4E)-α-acid 2 into three metabolites. (−)-4′-Hydroxy-α-acid 3 was a diastereoisomeric mixture consisting of major 1′,4′-trance-4′-hydroxy-α-acid 3a and minor 1′,4′-cis-4′-hydroxy-α-acid 3b. These structures, 3a and 3b, were confirmed by 13C-NMR and 1H-NMR analysis. Also, the enantioselectivity of the microbial oxidation was reexamined by using optically pure α-acid (+)-2 and (−)-2, as the substrates." @default.
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- W2029253651 date "1983-01-01" @default.
- W2029253651 modified "2023-10-02" @default.
- W2029253651 title "The metabolism of (2Z,4E)-.ALPHA.-ionylideneacetic acid in Cercospora cruenta, a fungus producing (+)-abscisic acid." @default.
- W2029253651 doi "https://doi.org/10.1271/bbb1961.47.1895" @default.
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