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- W2029275144 abstract "Abstract Two crystals of triazine derivatives, 2,4-diamino-6-benzyl-1,3,5-triazine (1) and 2,4-diamino-6-(4′-methylbenzyl)-1,3,5-triazine (2), are synthesised by a direct reaction of cyanoguanidine with the respective cyanocompounds. The IR spectra of the compounds are very similar. In the crystals the molecules are interconnected by N H⋯N hydrogen bonds forming one-dimensional hydrogen bonded polymer in 1 and three-dimensional hydrogen bonded network in 2. The arrangement of molecules in the crystal of 1 is denser than in 2 due to the π–π interactions between the π-clouds of the aromatic triazine rings that are absent in the crystal of 2. The geometries of the molecules in the crystals have been compared with those obtained by ab-initio molecular orbital calculated results that represent the geometries of molecules in the gas-phase." @default.
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- W2029275144 date "2009-02-01" @default.
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- W2029275144 title "Supramolecular hydrogen-bonded 1D arrangement in the crystals of 2,4-diamino-6-benzyl-1,3,5-triazine and 2,4-diamino-6-(4′-methylbenzyl)-1,3,5-triazine" @default.
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- W2029275144 doi "https://doi.org/10.1016/j.molstruc.2008.10.035" @default.
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