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- W2029283409 abstract "Synergic effects between ancillary N-heterocyclic carbenes [(1,3-bis(2,4,6-trimethylphenyl)-1,3-imidazoline-2-ylidene or 1,3-bis(2,6-diisopropylphenyl)-1,3-imidazoline-2-ylidene] and chelating benzylidene–ether ligands were investigated by studying initiation rates and kinetic profiles of Hoveyda–Grubbs (HG) type Ru complexes. A newly designed Ru-benzylidene-oxazinone precatalyst 4 was compared with Grela and Blechert complexes bearing modified isopropyloxy chelating leaving groups and with the standard HG complex to understand how the ancillary and the leaving ligands interact and influence the catalytic activity." @default.
- W2029283409 created "2016-06-24" @default.
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- W2029283409 date "2013-01-23" @default.
- W2029283409 modified "2023-10-07" @default.
- W2029283409 title "Synergic Effects Between N-Heterocyclic Carbene and Chelating Benzylidene–Ether Ligands Toward the Initiation Step of Hoveyda–Grubbs Type Ru Complexes" @default.
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- W2029283409 doi "https://doi.org/10.1021/cs400013z" @default.
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