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- W2029316523 abstract "The intensity of the band at |Δν|≌ 280 cm−1 in the Raman spectra of liquid methanol and methanol-d1 as a function of temperature in the region 178–298 K has been used to determine the equilibrium constant between free and hydrogen-bonded species and the average enthalpies of hydrogen-bond formation. The following values of enthalpies were obtained: ΔH0 = −11.3 ± 0.1 kJ mol−1 for CH3OH and −11.4 ± 0.1 kJ mol−1 for CH3OD. These values are similar to that of the enthalpy of formation of a single hydrogen-bond and confirm that there is one hydrogen-bond per methanol molecule in the liquid over the temperature range studied." @default.
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- W2029316523 date "1990-04-01" @default.
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- W2029316523 title "A quantitative raman spectroscopic study of hydrogen-bonding in methanol and methanol-d1" @default.
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- W2029316523 doi "https://doi.org/10.1016/0022-2860(90)80111-v" @default.
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