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- W2029333896 abstract "Alkyliron(III) porphyrin iron-carbon bond homolysis at ambient temperature yields a putative steady-state concentration of alkyl radicals. Homolytic decomposition by radical coupling and other reactions becomes auto-limiting due to competitive capture of subsequently formed alkyl radicals by the iron(II) porphyrin product. This reaction sequence is supported by radical-transfer crossover reactions in which the alkyl ligand of an alkyliron(III) porphyrin is transferred to another iron(II) porphyrin of different structure." @default.
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- W2029333896 title "Free radical-mediated electron transfer in organometallic complexes: homolysis and alkyl group crossover reactions for alkyliron(II) porphyrins" @default.
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- W2029333896 doi "https://doi.org/10.1016/0020-1693(94)04090-7" @default.
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