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- W2029335871 abstract "The rotational spectrum of the ethanol⋯argon van der Waals complex has been investigated by free-jet absorption millimeter-wave and molecular beams Fourier transform microwave spectroscopy. The spectra of normal and OD isotopomers have been assigned, but only for the complex with trans-ethanol. Ar motions produce vibrational splittings of 1.6662(7) and 1.70(2) MHz for the two isotopic species, respectively. The barrier hindering the tunnelling motion has been evaluated to be about 55 cm−1. The van der Waals structural parameters are: r0(Ar–O) = 3.56(1) Å, α0(∠ArOC) = 94°(1) and τ0(∠ArOCC) = 71°(1). The dissociation energy, as obtained from centrifugal distortion effects, is 2.1 kJ mol−1." @default.
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- W2029335871 date "2004-11-01" @default.
- W2029335871 modified "2023-09-28" @default.
- W2029335871 title "Free and pulsed jet rotational spectra and van der Waals motions of ethanol⋯argon" @default.
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- W2029335871 doi "https://doi.org/10.1016/j.cplett.2004.09.131" @default.
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