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- W2029366356 abstract "Fully exchanged, anhydrous ionomers of ethylene-co-acrylic acid (EAA) copolymers and ethylene-co-methacrylic acid (EMAA) copolymers containing Dy +3 , Er +3 , Sm +3 , Tb +3 , Tm +3 , and Yb +3 , and mixtures of them, were synthesized and studied in the near infrared region by reflection and Fourier Transform Laser Raman spectroscopies. The EAA copolymers ranged from 1.4 to 8.7 mol % acid and the EMAA copolymers were 7.3 and 16.2 mol % acid. The ionomers were shown to be essentially free of carboxylic acid groups, water, or other forms containing O-H groups and were characterized by infrared and other methods. They are light and heat stable, and become thermoplastic and moldable at ca. 220°C under pressure. When excited at 1.064 μ with a Nd : YAG laser, these ionomers exhibit novel, lanthanide-dependent near infrared luminescence and strong Raman scattering in the near infrared region. The strongest luminescence is observed with Sm +3 ionomers. The Dy +3 ionomer Raman-shifts this source to emit light most strongly in the 1.53-1.55 μ range where the ionomer also transmits light well." @default.
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- W2029366356 date "1996-01-15" @default.
- W2029366356 modified "2023-09-26" @default.
- W2029366356 title "Synthesis and near infrared properties of rare earth ionomers" @default.
- W2029366356 doi "https://doi.org/10.1002/(sici)1099-0488(19960115)34:1<151::aid-polb13>3.0.co;2-d" @default.
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