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- W2029385034 startingPage "2352" @default.
- W2029385034 abstract "The ultrasonic relaxation absorption has been measured in aqueous solution of dipentylamine, dihexylamine, dioctylamine, N-methylphenethylamine, and N-ethylbenzylamine in the presence of the sodium dodecyl sulfate(SDS) micelle. The relaxation absorption has been ascribed to the base equilibrium of the amines on the surface of the micelle: RR′NH2++OH−oversetkfundersetkbightleftharpoonsRR′NH+H2O. The rate constants γ±2kf, kb, the apparent base dissociation constant Kb (=kb⁄γ±2kf), and the volume change in the base equilibrium ΔV were obtained, where γ± is the mean activity coefficient for RR′NH2+ and OH−. The dependence of the rate constants on Kb revealed that, in the detailed mechanism of the base equilibrium of the amines, RR′underset(I)NH2++OH−oversetk12undersetk21ightleftharpoons(RR′NHunderset(II)2+···OH−)oversetk23undersetk32ightleftharpoonsRR′Nunderset(III)H+H2O, the rate-determining step is the proton-transfer process, (II) ightleftharpoons (III). The pKb values of the secondary amines ..." @default.
- W2029385034 created "2016-06-24" @default.
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- W2029385034 date "1984-09-01" @default.
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- W2029385034 title "Kinetic Studies of the Base Equilibrium of Secondary Amines on the Surface of Sodium Dodecyl Sulfate Micelle by Means of the Ultrasonic Absorption Method" @default.
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- W2029385034 doi "https://doi.org/10.1246/bcsj.57.2352" @default.
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