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• W2029408963 abstract "Abstract Amorphous films of ‘yellow arsenic’ composed of As4 molecules have been prepared by deposition from the vapour onto a substrate at 30 K in an X-ray diffractometer. X-ray diffraction measurements have been made at 30 K and at higher temperatures, and radial distribution functions determined. The local structure may be successfully modelled by staggered face-to-face packing of As4 tetrahedra, but attempts to model the longer range packing of As4 tetrahedra using quasi-crystalline models have had only limited success. The molecular film readily polymerizes on heating, even for T < 80 K, and the final structure at ambient temperature closely resembles that of amorphous β-arsenic." @default.
• W2029408963 created "2016-06-24" @default.
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• W2029408963 date "1981-10-01" @default.
• W2029408963 modified "2023-09-23" @default.
• W2029408963 title "The structure of vapour-deposited films of molecular arsenic (As4)" @default.
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• W2029408963 doi "https://doi.org/10.1080/01418638108222585" @default.
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