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• W2029437041 abstract "The phonon sideband (PSB) of Eu3+ associated with the 7F0-5D2 transition was investigated for the B2O3Na2O glasses doped with 1 mol% Eu2O3. It was found that the coupling of the phonon mode with Eu3+ ions in the glasses was through B-O− or B-O stretching vibration of BO3 units and vibrations of BO4− units in tetra- and diborate groups. The results showed that B-O− bonds present around Eu3+ ions, which have the highest phonon energy, contributed to the nonradiative decay by multiphonon relaxation of Eu3+ ions even in low-alkali borate glasses. Moreover, the electron-phonon coupling strength of each borate group was found to be influenced by the fraction present and by the site selectivity of Eu3+ ions for the group." @default.
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• W2029437041 date "1990-06-01" @default.
• W2029437041 modified "2023-10-18" @default.
• W2029437041 title "Phonon sideband of Eu3+ in sodium borate glasses" @default.
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• W2029437041 doi "https://doi.org/10.1016/0022-3093(90)90225-b" @default.
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