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- W2029444377 abstract "The optical properties of Pd atoms isolated in Ne, Ar, Kr, and Xe have been studied in the photon energy range of 2–10 eV by absorption, emission, and emission-yield spectroscopy. Strong matrix effects on the optical transitions are observed which lead to a breakdown of the selection rules and, hence, make a band assignment by AMCOR (atom to matrix correlation) impossible. The unusually large blue shift of the Pd 4d→5p transitions is rationalized by an interstitial site for the Pd atom in all four noble gas matrices. Such a site assignment is supported by the high mobility of the Pd atoms which becomes apparent in annealing experiments. For Pd in Ne, absorption bands due to 4d→4f transitions were found around 8 eV. Finally, a transient-absorption spectrum from a metastable state has been observed, which is in agreement with previously reported MCD measurements." @default.
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- W2029444377 date "1985-12-15" @default.
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- W2029444377 title "Optical spectra of matrix-isolated palladium atoms" @default.
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