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• W2029447405 endingPage "4444" @default.
• W2029447405 startingPage "4441" @default.
• W2029447405 abstract "In broad daylight: The double-decker thiostannate [(RSn(IV))(4)S(6)] (1, R = CMe(2)CH(2)COMe) condenses to form [{(RSn(IV))(2)(mu-S)(2)}(3)Sn(III)(2)S(6)] (2; see picture). This mixed-valent complex, which formally contains both Sn(III) and Sn(IV) atoms as confirmed by Mössbauer spectroscopy and DFT calculations, forms by a complicated, concerted mechanism. Additionally, 2 provides six carbonyl groups for further derivatization." @default.
• W2029447405 created "2016-06-24" @default.
• W2029447405 creator A5009236644 @default.
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• W2029447405 creator A5076273697 @default.
• W2029447405 date "2009-06-02" @default.
• W2029447405 modified "2023-09-23" @default.
• W2029447405 title "Thiostannate Tin-Tin Bond Formation in Solution: In Situ Generation of the Mixed-Valent, Functionalized Complex [{(RSn^IV)₂(μ-S)₂}₃Sn^III₂S₆]" @default.
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• W2029447405 doi "https://doi.org/10.1002/anie.200805719" @default.
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