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- W2029451609 abstract "The preparation of a series of rhodium(I) complexes with halogen- or methyl-substituted 1,3-dienes by displacement of ethylene from [(C2H4)2RhCl]2and [(C2H4)2Rh(acac)](acac = acetylacetonato) is described. The corresponding π-cyclopentadienyl complexes have also been prepared. The complexes have been characterized by means of 1H n.m.r., i.r., and mass spectra and by their chemical reactions. All the dienes studied co-ordinate to the metal in a chelate fashion with the exception of 4-methylpenta-1,3-diene which co-ordinates via the unsubstituted double bond only in the case of the chloro- and acetylacetonato-complexes. In solution the latter complexes exhibit temperature-dependent rotation of the co-ordinated diene about the rhodium–olefin bond axis. Possible reasons for the different co-ordination modes are discussed." @default.
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- W2029451609 date "1973-01-01" @default.
- W2029451609 modified "2023-10-11" @default.
- W2029451609 title "Transition-metal complexes of 1,3-dienes. Part I. Synthesis and structure of rhodium(I) complexes" @default.
- W2029451609 doi "https://doi.org/10.1039/dt9730002195" @default.
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