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• W2029477717 abstract "Radiation-induced precipitation was observed in α-annealed Zircaloy-2 irradiated in a flux of ~ 9.7 × 1017 n m−2 s−2 (E > 1 MeV) in the EBR-2 reactor to ~7.4 × 1024 n m−2 at 875 K. The precipitates were either rod-shaped Zr-Sn-Cr-Fe or hexagonal discs of a Zr-Sn phase containing traces of Fe. While the crystal structure of the former could not be determined by electron microdiffraction due to their small size, that of the latter was shown to be Zr5Sn3, the orientation relationship of which was (0001)ppt ∥(0001)Zr, [21&#x0304;1&#x0304;0]ptt ∥[51&#x0304;4&#x0304;0]Zr. The homogeneous precipitation of these Zr-Sn intermetallics is thought to result from irradiation-enhanced diffusion and a strong interaction between Sn atom clusters and vacancies. Vacancy-interstitial recombinati at solute clusters is believed to inhibit solute emission, thus stabilizing the clusters and eventually forming metastable precipitates of Zr5Sn3. The incorporation of Fe in this phase by self-interstitial replacement is consistent with this precipitation mechanism. Some possible implications of these observations to the behaviour of reactor alloys are suggested." @default.
• W2029477717 created "2016-06-24" @default.
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• W2029477717 date "1988-10-01" @default.
• W2029477717 modified "2023-10-09" @default.
• W2029477717 title "Radiation-induced precipitation in Zircaloy-2" @default.
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• W2029477717 doi "https://doi.org/10.1016/0022-3115(88)90106-7" @default.
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