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- W2029488914 abstract "Three series of cholesteryl esters with different linkages and terminal groups have been synthesised and characterised. All the esters except cholesteryl 6-bromohexanoate can exhibit thermotropic liquid crystalline phases in certain temperature regions. The insertion of a 4-phenoxyl and a 4-biphenylyloxy group in the ester can increase the molecular length, broaden the whole mesophase width and heighten the clearing temperature. The increasing molecular length can enforce the layered arrangement in series A and B (resulting in a monolayer smectic A phase), while destroying the layer stacking in series C (resulting in a suppressed or absent interdigitated smectic A phase). Meanwhile, the molecular structure played an important role in the molar helical twisting power and its temperature dependence." @default.
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- W2029488914 date "2011-07-01" @default.
- W2029488914 modified "2023-10-16" @default.
- W2029488914 title "Influence of linkage and terminal group on the liquid crystalline and helical twisting behaviours of cholesteryl esters" @default.
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- W2029488914 doi "https://doi.org/10.1080/02678292.2011.576780" @default.
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