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• W2029504524 abstract "In this paper, the synthesis of a crosslinkable co-polymer containing new push–pull arylethynyl zinc porphyrins is described. The synthesis of porphyrin chromophores, analogous to Therien's porphyrin (J. Am. Chem. Soc. 1996, 118, 1497–1503) functionalized with a methacrylic polymerizable group and a carboxylic acid crosslinking group was achieved with a new synthetic procedure leading to a higher overall yield compared to what was previously reported in the literature for similar and simpler structures. Radical copolymerization of the porphyrin chromophore with glycidyl methacrylate has then been carried out with success. This work opens a perspective on the possibility to integrate porphyrinic chromophore with high first-order molecular quadratic hyperpolarizability coefficient in opto-electronic devices." @default.
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• W2029504524 date "2005-10-01" @default.
• W2029504524 modified "2023-10-17" @default.
• W2029504524 title "Synthesis of new crosslinkable co-polymers containing a push–pull zinc porphyrin for non-linear optical applications" @default.
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• W2029504524 doi "https://doi.org/10.1016/j.tet.2005.07.094" @default.
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