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- W2029508913 abstract "The solvolysis rates of (1-arylcyclobutyl)methyl and (1-arylcyclopropyl)methyl p-toluenesulfonates were measured in a wide variety of solvents. The aryl-assisted kΔ solvolysis of [1-(p-methoxyphenyl)cyclobutyl]methyl p-toluenesulfonate did not give a linear Winstein–Grunwald correlation using the 2-adamantyl-based YOTs scale, but did show dispersion for different binary solvent mixtures. An extended dual-parameter treatment, log (k/k80E) = mcYOTs + mΔYΔ, successfully correlated the present set of kΔ solvolyses with R > 0.995 and SD < 0.09. The blending parameter MΔ (= 0.51mΔ/(mc + 0.51mΔ)) increases monotonically with increased electron donation by the substituent, showing an increased dispersion of the YOTs plot with increasing anchimeric assistance. The solvolysis of (1-arylcycloalkyl)methyl p-toluenesulfonates demonstrates the varying extent of anchimeric assistance by the neighboring groups, from a completely synchronous aryl-assisted process for the p-methoxy derivative of (1-phenylcyclobutyl)methyl ..." @default.
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- W2029508913 date "1996-03-01" @default.
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- W2029508913 title "Solvent Effects on Anchimerically Assisted Solvolyses. III. Solvent Effects on the Solvolyses of (1-Arylcycloalkyl)methylp-Toluenesulfonates" @default.
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